Yep. While the term can be a bit fluid, "Charted Space" seems to apply most often to the reach of the old red line map from GDW. If you back out a bit, it was digitized into Traveller Map. The corners are Sidiadl, Kring Noor, Treece, and Yahehwe. But. The Alien Books from later in CT pushed the named sectors out by a row all around, so maybe the edge of Charted Space is Viajlefliez, Xeeleer, Sporelex, and Aftailr. Later books pushed that out even farther in a few spots, so...
Named sectors beyond that are the result of various parties, whether Marc, Mongoose, or ardent fans, wanting to head into the unknown. When the sectors in Mongoose's Rimward book were transcribed for inclusion in Traveller Map, we noticed that the wiki put Betelgeuse in one of those sectors and decided to confirm that. The result was that Betelgeuse was moved to *about* where it should be.
On the other hand, the Pleiades are right in the way on the edge of Lubbock and Holowon, and accidentally make the approach into Lubbock mentioned in the Mongoose book the logical one. The Solomani route is implied to swing to spinward and approach Horden (Lubbock H) from spin-coreward. The Pleiades roughly occupy Lubbock C and D and likely parts of Holowon O and P. The cluster includes a LOT of stars, so jump travel through the Pleiades is likely very difficult, and the trailing side of the cluster has a polity that may not appreciate Solomani traffic. So the Solomani go around the other way.