Except by this time, it would be easier to tailor a virus that could kill not just planets, but whole subsectors with much less effort than a bunch of kinetic kill weapons. However, this runs against reality, such as today, where genocide, and genocidal weapons of mass destruction, simply aren't used. Functional NBC warfare was developed during WW2, but for the most part, except for cases like http://en.wikipedia.org/wiki/Unit_731 or the bombing of Nagasaki and Hiroshima, it never becomes standard procedure.
Yes. Biological warfare is also a threat. Biological weapons have problems of their own. You can get a virus that quickly kills virtually everyone who contracts it, a super-Ebola, but if it kills its victims before they can transmit it to others then it may not spread well. Flu viruses are so persistent because they don't kill everyone who gets them and they inflict symptoms (coughing and sneezing) that spread the virus. Develop something that can stay airborne for long periods of time, not killed as quickly by ultraviolet light, long latency period so people infected will move around and infect others before they get sick and die - can present a problem if someone picks up the virus and carries it by starship to your world.
The biggest problem faced in using such WMDs is that the truly massive/effective attacks require the resources of an interstellar government or mega-corporation. It isn't easy to hide who was responsible and executing such an attack may invite retaliation by the victim government or by your neighbors who decide they must pre-emptively strike you before you can do the same to them.
Civilian leadership generally seeks to avoid wars because war is messy. You look at our history with major powers possessing nuclear and other WMDs. The difference between Japan 1945 and Vietnam 1965 is in 1945 only one nation had such weapons. Later, when you have to be concerned about whether someone else will use their weapons, you start getting more careful.
Wasn't the motto of the USA Strategic Air Command "Our Profession is Peace". Possessing a massive force of bombers designed to deliver nuclear bombs but their purpose is avoiding their use? Yes. The point was to present such an overwhelming threat to anyone who attacks you that no one dares to let a war go nuclear.
So the Imperial Navy demonstrates some massive kinetic missiles against some moon designated as a test-firing range when they know that foreign agents are watching covertly - because they aren't intending to use them in a sneak attack but instead want the Zhodani to be cautious about provoking the use of these weapons in retaliation.