Solid State hydrogen

phavoc

Emperor Mongoose
The Nov 4 Aviation week magazine had an article on a company called H2MOF (https://h2mof.com/our-technology/) that has pioneered a new way to store hydrogen. Here's the crux of the article -
"MOF are nanoengineered materials in which metal ions are connected by organic ligands to create porous polymers. “It is a crystalline framework that has an incredible amount of surface area,” Bach says. “One gram is going to have an outside surface area of 1 m2 [11 ft.2], but because of the pores inside it, the internal surface area is around 7,000 m2.

“The more surface area, the more parking lots you have for water or carbon dioxide or hydrogen,” he says. “It’s just a very efficient parking lot for molecules. And the molecules are not being absorbed. They are hovering on the surface with weak bonding. That means it doesn’t require a lot of energy to discharge.”

The crystalline material is formed into pellets and loaded into tanks. Hydrogen is stored at relatively low pressure, around 20 bar, reducing tank weight and cost and allowing for noncylindrical shapes. Only a small amount of heat—either from the ambient air or waste heat from a fuel cell—is needed to release the hydrogen.

The tank can be recharged directly from the low-pressure outlet of an electrolyzer, and the hydrogen is durably and efficiently stored in a solid concrete-like form. This approach avoids the safety risks of high-pressure tanks exploding or cryogenic liquid tanks leaking, H2MOF points out.
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Basically using a polymer framework they are able to massively increase the density of the hydrogen and store it more like (wet) concrete. It doesn't need much pressurization or heat to remove the hydrogen from the polymer framework.

It's still in the development stage, but they are working on trying to create a drone that utilizes hydrogen stored like this as its fuel - "H2MOF has scaled up production of MOF to the kilogram level and produced prototype tanks, and now it is looking to partner with drone manufacturers to test the tanks beginning early next year, Chief Technology Officer Neel Sirosh says. Drones require 100-200 g of hydrogen, and the tanks are 6 in. in diameter and about 2 ft. long."

Metallic hydrogen is around double liquified hydrogen. This polymermized version takes it to a new level though. Will be interesting to see if they can get it to work. If so it can really help with the cost to distribute and store hydrogen. If it works, and it's applied to the game, it would change a lot of things!
 
No. Metallic hydrogen has a different molecular makeup than this polymerized version. Think of it this way - you have your hydrogen molecules that are liquefied and under pressure. Like the collapsed matter armor, you still have a lot of space in between each molecule. In this polymer version you collapse a lot of the free space, thus you can fit more things in the same volume. This polymer version also deals with the losses related to sublimation and pressurization that hydrogen storage has today.

A perfect example is having an 16oz glass. If you fill it up with large ice cubes you only have say 8 oz of fluid in there. If you take the ice out and chill the beverage itself you get the full 16oz of liquid in the glass with no wasted space.

Just how much they'll be able to shrink it down isn't clear, though they do mention they are looking at a 1 to 7000 size ratio. Just how much they are able to fully carry into a functional system remains to be seen once they have completed their next pilot phase. Even a 1 to 1000 improvement will massively skew how much hydrogen can be stored in the same size tank.
 
Where does the link you provided say anything about metallic hydrogen or shrinking storage capacity relative to cryogenic hydrogen? Most of what they have implies the opposite. Their tech is lower density, but safer and easier to store. This is what I was comparing to the metal hydride.
 
The link is for the company website. The italics are the snippet quotes from the AvWeek article. The article does compare/contrast some of the issues related to storing standard liquefied hydrogen and storing it as metallic hydrogen - "Hydrogen can be stored as a compressed gas at 350 or 700 bar (5,000 or 10,000 psi) or as a cryogenic liquid at temperatures below -253C (-423F). Compression uses up to 20% of the stored energy, while liquefaction and boil-off can consume up to 45%. Hydrogen also can be stored in solid form in metal hydrides, but this is heavy and requires high temperatures—about 300C—to release the hydrogen."

The method they are proposing combines some of the properties of each - but with an even greater capacity for storage and without the downsides that they two types of storage have.

I didn't post the entire article so I wouldn't run afoul of AvWeek claiming theft. I tried to post (and comment) on just the relevant portions of the article to stay within fair use guidelines.
 
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